Standoff - Season 1 - Eps 13: Backfire
Matt and Emily negotiate with two armed bank robbers who take a subway full of hostages. During the negotiation Matt is pulled away to deal with an hostage taker who Matt has met and successfully negotiated with, who has taken a therapist and the therapist's husband hostage. Matt talks the man who believes that an Evil Psychic Agent has taken the form of the therapist husband.
About Standoff

Title: Standoff
First Air Date: 2006-09-05
Last Air Date: 2007-07-20
Status: Ended
Rating: 6/10 (from 14 votes)
Language: EN
Seasons: 1
Total Episodes: 18
Network: FOX
Genres: Drama, Crime
Production Companies: Sesfonstein Productions
Synopsis
The series focused on an FBI Crisis Negotiation Unit whose members negotiated hostage situations and shared relationships.
Cast

Michael Cudlitz
Frank Rogers

Ron Livingston
Matt Flannery

Raquel Alessi
Lia Mathers

Jose Pablo Cantillo
Duff Gonzalez

Rosemarie DeWitt
Emily Lehman

Gina Torres
Cheryl Carrera