Invader ZIM - Season 1 - Eps 9: The Wettening
When it begins to rain one day, Zim becomes worried because he’s never experienced rain before. Dib takes notice of his fear and he coaxes Zim into stepping into the rain, only to discover that the Irken race has an innate weakness to water, which causes a burning sensation upon impact. Dib decides to exploit this new fact to create the ultimate weapon to stop Zim once and for all, but Zim himself attempts to find a way to protect himself from this new found weakness, which all leads up to a confrontation that neither of them would have expected.
About Invader ZIM

Title: Invader ZIM
First Air Date: 2001-03-30
Last Air Date: 2006-08-19
Status: Canceled
Rating: 8.429/10 (from 392 votes)
Language: EN
Seasons: 3
Total Episodes: 46
Network: Nickelodeon
Genres: Animation, Sci-Fi & Fantasy, Comedy, Kids
Production Companies: Nickelodeon Animation Studio
Synopsis
Zim dreams of greatness. Unfortunately, though, he's hopelessly inept as a space invader. Desperate to be rid of the annoying Zim, his planet's leaders send him on a mission to infiltrate Earth, providing him with leftover, cobbled-together equipment. To their consternation, Zim succeeds in setting up a base on Earth and infiltrating human culture, posing as a human child as he plots the planet's downfall. Only Zim's archnemesis, Dib, recognizes that Zim is an alien, and of course, nobody believes Dib's claims.
Cast

Richard Steven Horvitz
Zim (voice)

Andy Berman
Dib (voice)

Rosearik Rikki Simons
GIR (voice)

Melissa Fahn
Gaz (voice)

Lucille Bliss
Ms. Bitters (voice)

Rodger Bumpass
Professor Membrane (voice)

Kevin McDonald
Almighty Tallest Purple (voice)